DNA Damage & Repair Oligonucleotide Modifications

Research-ready modified oligos that model oxidized, alkylated, abasic, and UV-induced lesions to interrogate BER/NER pathways, mutagenesis, and therapeutic resistance—delivered with ISO 9001/13485 quality and RUO→GMP-like workflows.

45+ Years ISO 9001 / 13485 RUO → GMP-like Bench → Kilo

Overview

Bio-Synthesis offers a comprehensive portfolio of DNA damage & repair oligonucleotide modifications that faithfully mimic endogenous lesions—8-oxo-dG/dA and thymidine glycol (oxidation), O6-Me-dG and O4-Me-dT (alkylation), stable abasic mimics (dSpacer, Pyrrolidine), and UV dimers (CPD, cis-syn TT). Use these controls to quantify enzyme kinetics, map pathway preferences (BER, NER, MMR), validate diagnostic assays, and de-risk therapeutic designs.

We combine scientist-to-scientist design support with in-house synthesis, custom purification (HPLC/UPLC, PAGE), and full analytics (LC-MS, OD260; optional endotoxin/residuals/stability). Supply scales range from discovery µmol to bench-to-kilo, backed by ISO 9001/13485 quality and RUO→GMP-like documentation for smooth tech transfer.

45+ Years ISO 9001 / 13485 RUO → GMP‑like Bench → Kilo

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Services at a Glance

Design & Conjugation

Lesion selection, placement, and density; sequence review; optional handles/spacers for assay geometry.

Analytics & QC

HPLC/UPLC, LC-MS, OD260; optional endotoxin/residuals; stability time-points; detailed CoAs.

Scale & Documentation

Discovery µmol → kilo-class; tubes/vials/plates with barcodes; ISO 9001/13485; RUO→GMP-like files.

Products for DNA Damage & Repair Studies

Oxidized & Cyclopurine Lesions

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Lesions used to study oxidative stress and BER fidelity

Product Description Application Code
8-Oxo-2'-deoxyguanosine Oxidized guanine base BER, oxidative DNA damage [8-oxo-dG]
8-Oxo-2'-deoxyadenosine Oxidized adenine base Oxidative stress marker [8-oxo-dA]
8,5'-cyclo-dA Cyclopurine adenine lesion Oxidative/UV cross-links; repair assays [8,5-Cyclo-dA]
8,5'-cyclo-dG Cyclopurine guanine lesion DNA damage modeling [8,5-Cyclo-dG]
Thymidine Glycol 5,6-dihydroxy-5,6-dihydro-T Oxidative stress repair [Thymidine Glycol]
5-Hydroxymethyl-2'-deoxyuridine Hydroxymethylated uridine Epigenetics, DNA repair [5-hme-dU]
5-Hydroxy dU Oxidized uracil analog DNA repair assays [5-OH-dU]
5-Hydroxy dC Oxidized cytosine BER analysis [5-OH-dC]
5,6-Dihydro-dT Dihydro thymidine lesion DNA structure/repair studies [5-6 DH-dT]
5,6-Dihydro-dU Dihydro uridine lesion Repair enzyme assays [5-6 DH-dU]
dihydro dUracil 5-6 DHdU damage analog DNA/RNA repair assays [5-6 DHdU]
2'-DeoxyXanthosine Xanthine analog DNA base damage studies [dX]
Design Notes: 8-oxo lesions increase mispairing; place in duplex regions to assess glycosylase specificity. Cyclopurines are helix-distorting; consider longer spacers if paired with conjugates.

Alkylated & Adduct Lesions

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Models for alkylation damage and mutagenesis

Product Description Application Code
O6-Methyl-2'-deoxyguanosine Methylated guanine lesion DNA repair, mutagenesis [O6-Me-dG]
O4-Methylthymidine Methylated thymidine analog Alkylation damage models [O4-Me-dT]
N3-Methyl-dC Methylated cytidine DNA alkylation damage [N3-Me-dC]
N6-Methyl dA Methylated adenine Epigenetics & DNA repair [N6-Me-dA]
Etheno deoxyadenosine dA Etheno adduct lesion Mutagenesis assays [Etheno dA]
Design Notes: For polymerase bypass studies, place O6-Me-dG opposite C or T to probe miscoding. Validate ligation/PCR behavior if the lesion sits near primer ends.

UV-Induced Lesions

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NER targets formed by UV exposure

NER targets formed by UV exposure
Product Description Application Code
Cis-Syn Thymidine Dimer UV photodimer lesion NER pathway research [Cis-Syn TT]
Cyclobutane Pyrimidine Dimer (CPD) UV-induced CPD lesion NER, photodamage repair [CPD]
Design notes: Include flanking sequence context (≥10 nt each side) to maintain NER recognition motifs.

Abasic & AP Site Mimics

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Stable analogs to probe BER incision/polymerase steps

Product Description Application Code
dSpacer Stable abasic (AP) site mimic DNA repair assays [Ab]
Pyrrolidine Cyclic abasic mimic BER mechanism analysis [Pyrrolidine]
Abasic II Stable abasic site DNA polymerase studies [Abasic II]
rAbasic RNA abasic site analog RNA repair studies [rAb]
Design Notes: Avoid positioning AP sites at termini; internal placement improves nuclease/ligase readouts.

Epigenetic Oxidation Series (5-hmC / 5-fC / 5-caC)

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Cytosine oxidation states for TET/BER pathway studies

Product Description Application Code
5-Hydroxymethyl dC II Hydroxymethyl cytidine Epigenetics, BER [Hydroxymethyl dC II]
5-Formyl dC III Formylated cytidine Epigenetic studies [Formyl dC III]
5-Formyl dC Formyl cytosine lesion Oxidative demethylation [Formyl dC]
5-Carboxy dC Carboxylated cytidine TET-mediated oxidation [5-COOH-dC]
Design Notes: For enrichment/antibody validation, include both strand contexts and matched unmodified controls.

Additional Analogs

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Useful controls and base analogs

Product Description Application Code
dU (deoxyuridine) Uracil in DNA DNA metabolism & BER assays [dU]
O6-Methyl dG Methylated guanine lesion Mutagenesis, repair assays [O6-Me-dG]
8-Amino-dG Amino-modified guanine DNA–protein crosslinking [8-Amino-dG]
8-Amino-dA Amino-modified adenine Mutagenesis models [8-Amino-dA]

Need help choosing lesions or designing a repair assay?

We’ll recommend lesion types, placement, purification, and QC—matched to your pathway and readout.

Applications in DNA Damage & Repair Research

Many DNA damage and repair studies focus on the mutagenic and genotoxic consequences that arise from specific single-base lesions such as 8-oxo-dG or O6-Me-dG. Increasingly, attention has turned to lesion clusters—multiple damaged bases occurring within a short stretch of DNA or on opposite strands. Clustered damage is particularly relevant to ionizing radiation, where repair efficiency and pathway choice differ significantly from single-lesion scenarios.

Another active research area is the role of sequence context (e.g., isolated guanines vs. runs of Gs) in determining both the number and type of lesions produced by oxidative agents. Such context effects influence repair enzyme recognition, misincorporation frequencies, and genome stability.

Custom incorporation of modified nucleotide phosphoramidites into oligonucleotides provides powerful tools to investigate these mechanisms. Bio-Synthesis supports applications including:

  • Mechanistic studies of base excision repair (BER), nucleotide excision repair (NER), and mismatch repair (MMR).
  • Assay development for detection of specific DNA lesions or monitoring repair processes in vitro and in vivo.
  • Environmental & toxicology testing—using lesion-containing oligos to screen for mutagenic or genotoxic compounds.
  • Therapeutic research—understanding how DNA damage contributes to cancer, aging, and treatment resistance.

References: Lodish et al., 2004; Lindahl, 1993; Nilsen & Krokan, 2001; de Laat et al., 1999; Iyer et al., 2006; Sancar, 2003; Shikazono et al., 2006; Margolin et al., 2008; Reardon & Sancar, 2003; Prakash & Prakash, 2000; Asagoshi et al., 2010; Sundaresakumar, 2009; Tornaletti & Pfeifer, 1996; Rochette & Brash, 2010.

DNA Damage Repair Design & Protocol

Successful DNA damage repair assays depend on carefully designed oligonucleotides that incorporate relevant lesions, matched with the correct detection method. Bio-Synthesis provides design consultation and custom synthesis of lesion-containing oligos for NER, BER, and UV-damage assays.

I. Nucleotide Excision Repair (NER)

NER is typically studied using synthetic oligo duplexes that carry bulky adducts (e.g., CPDs or cisplatin-type lesions). Standard in vitro assays employ cell-free extracts supplemented with six recombinant NER factors (RPA, XPA, XPC, TFIIH, XPG, XPF). These systems allow monitoring of lesion recognition, dual incision, and resynthesis steps.

II. Base Excision Repair (BER)

BER assays generally use duplex oligos containing lesions such as 8-oxo-dG, thymidine glycol, or uracil analogs. Whole-cell extracts or purified enzymes are used to follow glycosylase activity, AP endonuclease incision, and gap filling. BER can also be monitored in vivo using reporter constructs or damage-specific probes.

III. UV-Induced DNA Damage

UV lesions, including cyclobutane pyrimidine dimers (CPDs) and 6,4-photoProducts, are mapped using PCR-based methods such as ligation-mediated PCR (LMPCR). For repetitive regions like telomeres, immunoprecipitation of damaged DNA (IPoD) is preferred, enabling study of repair kinetics in otherwise intractable sequences.

Assay considerations:
  • Match lesion type to the repair pathway under investigation (BER vs NER vs UV-damage repair).
  • Use appropriate flanking sequence context—GC-rich vs AT-rich regions can alter repair efficiency.
  • Include controls: lesion-free duplexes and competitor substrates improve data interpretation.
  • Consider in vitro vs in vivo readouts depending on your biological question.

References: Reardon & Sancar, 2003; Prakash & Prakash, 2000; Asagoshi et al., 2010; Sundaresakumar, 2009; Tornaletti & Pfeifer, 1996; Rochette & Brash, 2010.

FAQ

What’s the difference between gapmers and steric‑block SSOs?

Gapmers recruit RNase H to cleave target RNA; SSOs modulate splicing or block translation without cleavage. Choose based on biology and delivery route.

Which lesions should I start with?

Common baselines are 8-oxo-dG (oxidation), O6-Me-dG (alkylation), a stable abasic (dSpacer or Pyrrolidine), and CPD for NER studies.

Do you provide plates and barcoded panels?

Yes—tubes, vials, and plates with labels/barcodes, normalized concentrations, and full CoAs are available.

Can you supply GMP or diagnostic-grade material?

We offer RUO, GLP, and GMP-aligned workflows with ISO 9001/13485 quality and comprehensive documentation.

How do I choose between 8-oxo-dG and thymidine glycol?

8-oxo-dG is a miscoding lesion suited for glycosylase fidelity and polymerase bypass; thymidine glycol is helix-distorting and useful for incision/NER recognition studies.

Speak to a Scientist

Please avoid confidential details; we can arrange an NDA if needed.

Why Choose Bio-Synthesis

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